Overview of advanced technologies for stabilization of {sup 238}Pu-contaminated waste

Conference · Sun Feb 01 04:00:00 EST 1998

DOI:https://doi.org/10.1063/1.54754· OSTI ID:650145

Ramsey, K B; Foltyn, E M ^[1]; Heslop, J M ^[2]

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1. Los Alamos National Lab., NM (United States)
2. Naval Surface Warfare Center, Indian Head, MD (United States)

This paper presents an overview of potential technologies for stabilization of {sup 238}Pu-contaminated waste. Los Alamos National Laboratory (LANL) has processed {sup 238}PuO{sub 2} fuel into heat sources for space and terrestrial uses for the past several decades. The 88-year half-life of {sup 238}Pu and thermal power of approximately 0.6 watts/gram make this isotope ideal for missions requiring many years of dependable service in inaccessible locations. However, the same characteristic which makes {sup 238}Pu attractive for heat source applications, the high Curie content (17 Ci/gram versus 0.06 Ci/gram for 239{sup Pu}), makes disposal of {sup 238}Pu-contaminated waste difficult. Specifically, the thermal load limit on drums destined for transport to the Waste Isolation Pilot Plant (WIPP), 0.23 gram per drum for combustible waste, is impossible to meet for nearly all {sup 238}Pu-contaminated glovebox waste. Use of advanced waste treatment technologies including Molten Salt Oxidation (MSO) and aqueous chemical separation will eliminate the combustible matrix from {sup 238}Pu-contaminated waste and recover kilogram quantities of {sup 238}PuO{sub 2} from the waste stream. A conceptual design of these advanced waste treatment technologies will be presented.

• Research Organization: Los Alamos National Lab., NM (United States)
• Sponsoring Organization: USDOE Assistant Secretary for Nuclear Energy, Washington, DC (United States)
• DOE Contract Number: W-7405-ENG-36
• OSTI ID: 650145
• Report Number(s): LA-UR--97-4368; CONF-980103--; ON: DE98003446
• Country of Publication: United States
• Language: English

Related Subjects

05 NUCLEAR FUELS
MATRIX MATERIALS
MOLTEN SALT WASTE GASIFICATION PROCESS
NESDPS Office of Nuclear Energy Space and Defense Power Systems
PLUTONIUM 238
RADIOACTIVE WASTE PROCESSING
SOLID WASTES