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Toxicity of trihalomethanes to common carp embryos

Journal Article · · Trans. Am. Fish. Soc.; (United States)

Trihalomethanes recently have been identified in real and simulated effluents from power plants where chlorine is used for biofouling control. Toxicity of the four chlorine- or bromine-containing trihalomethanes (chloroform, bromodichloromethane, dibromochloromethane, and bromoform) to developing common carp (Cyprinus carpio) embryos was determined under conditions of intermittent (8-hour) toxicant renewal, based on percent hatch as the end point. Nominal median lethal concentrations (LC50) ranged from 161 mg/liter for chloroform to 53 mg/liter for dibromochloromethane. Decay studies conducted under conditions similar to those used for the toxicity studies, but in distilled water, indicated that (1) half-lives of the trihalomethanes ranged from 4.4 to 6.9 hours; (2) decay was due primarily to volatilization; (3) higher relative toxicity of dibromochloromethane probably was due to formation of a degradation product (likely Br/sub 2/). Correction of the nominal LC50 values to time-weighted mean concentrations over the period between toxicant changes gave weighted LC50 values of 97.2, 67.4, 33.5, and 52.3 mg/liter for chloroform, bromodichloromethane, dibromochloromethane, and bromoform, respectively. In addition, the period of water-hardening of fertilized eggs was not critical for expression of toxicity of dibromochloromethane. Comparison of these and other published data on effluent and toxic concentrations, persistence, and bioaccumulation of water-chlorination products suggests that trihalomethanes are not as environmentally critical as other chlorinated organic compounds or residual chlorine.

DOE Contract Number:
W-7405-ENG-26
OSTI ID:
6495671
Journal Information:
Trans. Am. Fish. Soc.; (United States), Journal Name: Trans. Am. Fish. Soc.; (United States) Vol. 110:2; ISSN TAFSA
Country of Publication:
United States
Language:
English