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Title: Microstructures and mechanical properties of NiAl-Ni sub 2 AlHf alloys

Journal Article · · Journal of Materials Research; (USA)
 [1];  [2]
  1. National Research Institute for Metals, 2-3-12 Nakameguro, Meguro-ku, Tokyo 153 (Japan)
  2. Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN (USA)

The microstructure and mechanical properties of several Ni-Al-Hf alloys in the composition range between NiAl({beta}) and Ni{sub 2}AlHf (Heusler phase) have been studied. The volume fraction of Heusler phase, {ital V}{sub {ital f}}, in these alloys varies from about 15 to 96%. The lattice misfit between the {beta} and Heusler phases in two-phase alloys is larger than 5%, indicating no coherency between them. The yield strength increases with increasing {ital V}{sub {ital f}} at all temperatures to 1000 {degree}C. Compressive ductilities of 4 and 7% were obtained for the alloy with {ital V}{sub {ital f}} of 15% at room temperature and 500 {degree}C, respectively, but they decreased to 0% with increasing {ital V}{sub {ital f}} to 96%. The corresponding fracture mode is basically transgranular cleavage. However, all the alloys can be deformed extensively without fracture at 1000 {degree}C. The hardness of the Heusler alloy is very high (8.3 GPa) at room temperature, and it decreases gently with temperature to 600 {degree}C, followed by a rapid decrease to 1000 {degree}C. The brittleness and high hardness of the Ni{sub 2}AlHf Heusler phase at low temperatures are interpreted in terms of internal lattice distortion resulting from its crystal structure. The thermally activated process of deformation takes place above 600 {degree}C, which is responsible for the rapid drop of the hardness of the alloys.

DOE Contract Number:
AC05-84OR21400
OSTI ID:
6494422
Journal Information:
Journal of Materials Research; (USA), Vol. 5:6; ISSN 0884-2914
Country of Publication:
United States
Language:
English