Bridging ligands in organometallic chemistry. II. Synthesis and reactivity of the green dimer of molybdenocene containing a bridging fulvalene ligand
Journal Article
·
· Inorg. Chem.; (United States)
Synthesis, precipitation, and isolation of dicyclopentadienyl(fulvalene)dihydridomolybdenum are described. The compound was used in reaction studies involving the addition of carbon monoxide and deprotonation with n-butyllithium. Data for elemental analysis, ir spectral and NMR(in toluene-d) spectral analysis are reported for the title compound and its reaction products.
- Research Organization:
- Univ. of California, Berkeley
- OSTI ID:
- 6478937
- Journal Information:
- Inorg. Chem.; (United States), Vol. 17:11
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6478937
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON MONOXIDE
CHEMICAL REACTIONS
LITHIUM COMPOUNDS
MOLYBDENUM COMPLEXES
CHEMICAL REACTION YIELD
STRUCTURAL CHEMICAL ANALYSIS
ORGANOMETALLIC COMPOUNDS
INFRARED SPECTRA
LIGANDS
NUCLEAR MAGNETIC RESONANCE
ALKALI METAL COMPOUNDS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
COMPLEXES
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RESONANCE
SPECTRA
TRANSITION ELEMENT COMPLEXES
YIELDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON MONOXIDE
CHEMICAL REACTIONS
LITHIUM COMPOUNDS
MOLYBDENUM COMPLEXES
CHEMICAL REACTION YIELD
STRUCTURAL CHEMICAL ANALYSIS
ORGANOMETALLIC COMPOUNDS
INFRARED SPECTRA
LIGANDS
NUCLEAR MAGNETIC RESONANCE
ALKALI METAL COMPOUNDS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
COMPLEXES
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RESONANCE
SPECTRA
TRANSITION ELEMENT COMPLEXES
YIELDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties