Effect of the nature of a sulfur-containing catalyst on its activity in the reaction of carbonylation of nitrobenzene into methylene phenylurethane
Journal Article
·
· J. Appl. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6478212
Different sulfur containing compounds, including sulfides, sulfates, thiocyanates, xanthates, thio alcohols, sulfones, and heterocyclic sulfur-containing compounds, were used as catalysts of the reaction. The catalysts were loaded into the reactor in quantities corresponding to a constant number of g-atoms of sulfur (0.25) with respect to the nitrobenzene used. Data reported the efficiency of sulfur compounds which are the salt of different sulfur-containing acids which were determined by the character of both the cationic and the anionic part of the catalyst. The carbonylation of nitrobenzene by carbon monoxide in methanol in the presence of organic derivatives of sulfur is examined.
- Research Organization:
- Gor'kii State Univ. (USSR)
- OSTI ID:
- 6478212
- Journal Information:
- J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 60:6; ISSN JAPUA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ANTITHYROID DRUGS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONIC ACID DERIVATIVES
CARBONYLATION
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
DRUGS
EFFICIENCY
HORMONE ANTAGONISTS
HYDROXY COMPOUNDS
MATERIALS
MATERIALS TESTING
METHANOL
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASTICS
POLYAMIDES
POLYMERS
POLYURETHANES
PRODUCTION
SULFATES
SULFIDES
SULFONES
SULFUR COMPOUNDS
SYNTHETIC MATERIALS
TESTING
THIOCYANATES
XANTHATES
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ANTITHYROID DRUGS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONIC ACID DERIVATIVES
CARBONYLATION
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
DRUGS
EFFICIENCY
HORMONE ANTAGONISTS
HYDROXY COMPOUNDS
MATERIALS
MATERIALS TESTING
METHANOL
NITRO COMPOUNDS
NITROBENZENE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASTICS
POLYAMIDES
POLYMERS
POLYURETHANES
PRODUCTION
SULFATES
SULFIDES
SULFONES
SULFUR COMPOUNDS
SYNTHETIC MATERIALS
TESTING
THIOCYANATES
XANTHATES