Dehydrogenation of cyclohexane on platinum-technetium catalysts

Journal Article · Wed Jul 01 04:00:00 EDT 1987 · Dokl. Chem. (Engl. Transl.); (United States)

OSTI ID:6478166

Spitsyn, A V.C.; Pirogova, G N; Popova, N N; Kalinina, G E

The model reaction used was the cyclohexane-dehydrogenation process where technetium displayed ample activity. Activity of the catalysts was studied on a pulsed catalytic unit at atmospheric pressure and the analysis of reaction products was carried out by gas chromatography. The condition of the surfaces of the catalysts produced was studied by means of the chemisorption of hydrogen and scattered-rebound spectra were recorded on a spectrophotometer. Characteristics of the catalysts are shown. The degree of cyclohexane conversion with the catalysts and benzene yield vs. the ratio of Pt to Tc for catalysts at 330 C are illustrated.

• OSTI ID: 6478166
• Journal Information: Dokl. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Chem. (Engl. Transl.); (United States) Vol. 292:1; ISSN DKCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALINE EARTH METAL COMPOUNDS
ALKANES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AROMATICS
BENZENE
CATALYSIS
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISORPTION
CHROMATOGRAPHY
CYCLOALKANES
CYCLOHEXANE
DEHYDROGENATION
ELEMENTS
GAS CHROMATOGRAPHY
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN
MAGNESIUM COMPOUNDS
MAGNESIUM OXIDES
MATERIALS TESTING
METALS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM
PLATINUM METALS
QUANTITY RATIO
SEPARATION PROCESSES
SILICON COMPOUNDS
SILICON OXIDES
SORPTION
SPECTROPHOTOMETRY
SURFACE PROPERTIES
TECHNETIUM
TESTING
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
YIELDS
YTTRIUM COMPOUNDS
YTTRIUM OXIDES