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Reactions of perfluoro-1-alkylcycloalkenes with alcohols and properties of vinyl ethers formed (in Russian)

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00956599· OSTI ID:6476789
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Perfluoro-1-alkylcycloalkenes react with alcohols to form products of vinyl and allyl substitution. Alkyl perfluorocycloakenyl ethers readily alkylate the fluoride ion and triethylamine, and by the action of SbF/sub 5/ convert into ..cap alpha.., ..beta..-unsaturated perfluoro ketones. When allyl perfluorocycloalkenyl ethers are heated, they isomerize into the corresponding ..cap alpha..-allylperfluorocycloalkanones.

Research Organization:
A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
OSTI ID:
6476789
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:6; ISSN BACCA
Country of Publication:
United States
Language:
Russian

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKENES
ALKYLATION
ANIONS
ANTIMONY COMPOUNDS
ANTIMONY FLUORIDES
CARBANIONS
CATALYTIC EFFECTS
CHARGED PARTICLES
CHEMICAL REACTIONS
CYCLOALKENES
ELECTRON SPIN RESONANCE
ETHERS
FLUORIDES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINE 19
FLUORINE COMPOUNDS
FLUORINE ISOTOPES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN 1
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INFRARED SPECTRA
IONS
ISOMERIZATION
ISOTOPES
KETONES
LIGHT NUCLEI
MAGNETIC RESONANCE
MONOMERS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
RESONANCE
SPECTRA
STABLE ISOTOPES
SYNTHESIS
VINYL MONOMERS