Stable polyfluorinated cycloalkenyl cations and their NMR spectra
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:6475876
New stable 1-methoxyperfluoro-2-ethylcyclobutenyl, 1-methoxyperfluoro-2-methylcyclo-pentenyl, and 1-methoxyperfluoro-2-ethylcyclohexenyl cations were obtained by the action of antimony pentafluoride on the corresponding olefins. The distribution of the charges in the investigated polyfluorinated cycloalkenyl cations was investigated by /sup 13/C NMR method.
- Research Organization:
- A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
- OSTI ID:
- 6475876
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:10; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKENES
ANGULAR MOMENTUM
ANTIMONY COMPOUNDS
ANTIMONY FLUORIDES
CARBON 13
CARBON ISOTOPES
CATALYTIC EFFECTS
CATIONS
CHARGE DISTRIBUTION
CHARGED PARTICLES
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
CYCLOALKENES
EVEN-ODD NUCLEI
FLUORIDES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINE 19
FLUORINE COMPOUNDS
FLUORINE ISOTOPES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INTERMEDIATE COUPLING
IONS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PARTICLE PROPERTIES
SPECTRA
SPIN
STABLE ISOTOPES
SYNTHESIS
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKENES
ANGULAR MOMENTUM
ANTIMONY COMPOUNDS
ANTIMONY FLUORIDES
CARBON 13
CARBON ISOTOPES
CATALYTIC EFFECTS
CATIONS
CHARGE DISTRIBUTION
CHARGED PARTICLES
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
CYCLOALKENES
EVEN-ODD NUCLEI
FLUORIDES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINE 19
FLUORINE COMPOUNDS
FLUORINE ISOTOPES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INTERMEDIATE COUPLING
IONS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PARTICLE PROPERTIES
SPECTRA
SPIN
STABLE ISOTOPES
SYNTHESIS