Kinetic study of radical-aromatic hydrocarbon reactions. Annual progress report No. 3, 1 May 1980-31 March 1981

Technical Report · Thu Apr 02 23:00:00 EST 1981

DOI:https://doi.org/10.2172/6468468· OSTI ID:6468468

During the last 12 months, the analysis of some of the data on OH reactions with benzene and toluenes were completed. The following OH reactions were also studied: OH + o-xylene ..-->.. products at 298-870 K; OH + m-xylene ..-->.. products at 250-970 K; and OH + p-xylene ..-->.. products at 298-970 K. This work is now complete and has been written up for publication in the Journal of Physical Chemistry. Apart from the above-mentioned OH reactions, the following O(/sup 3/P) reactions have been studied utilizing the flash photolysis-resonance fluorescence technique: O(/sup 3/P) + C/sub 6/H/sub 6/ ..-->.. products at 298-870 K (1); O(/sup 3/P) + C/sub 6/D/sub 6/ ..-->.. products at 298-806 K (2); O(/sup 3/P) + C/sub 6/H/sub 5/CH/sub 3/ ..-->.. products at 298-930 K (3); O(/sup 3/P) + C/sub 6/H/sub 5/CD/sub 3/ ..-->.. products at 298-930 K (4); O(/sup 3/P) + o-xylene ..-->.. products at 298-970 K (5); O(/sup 3/P) + m-xylene ..-->.. products at 298-970 K (6); and O(/sup 3/P) + p-xylene ..-->.. products at 298-970 K (7).

• Research Organization: Georgia Inst. of Tech., Atlanta (USA). Research Inst.
• DOE Contract Number: AS05-78ER06030
• OSTI ID: 6468468
• Report Number(s): DOE/ER/06030-T2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
AROMATICS
BENZENE
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL REACTORS
COMPARATIVE EVALUATIONS
DECOMPOSITION
DESIGN
ELEMENTS
EQUIPMENT
FLUORESCENCE
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXYL RADICALS
KINETICS
LUMINESCENCE
MEDIUM TEMPERATURE
NONMETALS
ORGANIC COMPOUNDS
OXYGEN
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
REACTION KINETICS
RESEARCH PROGRAMS
TOLUENE
WATER
XYLENES