Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Carbanion photochemistry. 11. 1,3-diphenylisoindenylidene

Journal Article · · J. Am. Chem. Soc.; (United States)
DOI:https://doi.org/10.1021/ja00331a023· OSTI ID:6461393
The irradiation of 2-chloro- or 2-bromo-1,3-diphenylindenyl anion causes dehalogenation to yield a hypovalent intermediate best described as 1,3-diphenylisoindenylidene or 1,3-diphenyl-1,2-dehydroindene. This intermediate undergoes facile CH insertion, addition to electron-rich olefins, and halide interchange. 23 references, 6 figures, 1 table.
Research Organization:
Univ. of Kentucky, Lexington
OSTI ID:
6461393
Journal Information:
J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 106:19; ISSN JACSA
Country of Publication:
United States
Language:
English