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Determination of the calibration constant of the isomer shift of /sup 57/ Moessbauer spectra

Journal Article · · Theor. Exp. Chem. (Engl. Transl.); (United States)
OSTI ID:6456543
Results are presented from quantum-chemical calculations for the iron complexes Fe(CN)/sub 5/NO/sup 2 -/, Fe(CN)/sub 6//sup 3 -/, Fe(CN)/sub 6//sup 4 -/, FeCl/sub 4//sup -/, and FeCl/sub 6//sup 3 -/ in comparison with Moessbauer-spectroscopic data. The parameters of the Moessbauer spectra were calculated according to specially developed programs. The calibration constant of the isomer shift ..cap alpha.. was determined to be -0.13 mm/sec.
Research Organization:
Institute of Biophysics, Moscow (USSR)
OSTI ID:
6456543
Journal Information:
Theor. Exp. Chem. (Engl. Transl.); (United States), Journal Name: Theor. Exp. Chem. (Engl. Transl.); (United States) Vol. 23:4; ISSN TEXCA
Country of Publication:
United States
Language:
English