Spectroscopic studies of transition-metal ions in molten alkali-metal carboxylates

Conference · Wed Dec 01 00:00:00 EST 1982

OSTI ID:6448245

Maroni, V A; Maciejewski, M L

This paper presents the results of electronic absorption and /sup 13/C-NMR measurements on molten alkali metal formates and acetates and on solutions of selected 3d transition metal ions therein. These studies provide a unique opportunity to explore (1) the highly ordered nature of alkali carboxylates, (2) the ligand field properties of acetate and formate ions, and (3) the coordination chemistry of the 3d transition metals in molten carboxylates. 1 figure, 2 tables.

• Research Organization: Argonne National Lab., IL (USA)
• DOE Contract Number: W-31-109-ENG-38
• OSTI ID: 6448245
• Report Number(s): CONF-830508-11; ON: DE83009610
• Resource Relation: Conference: Electrochemical Society meeting, San Francisco, CA, USA, 8 May 1983
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
ABSORPTION SPECTRA
NMR SPECTRA
CHROMIUM COMPOUNDS
FORMATES
IRON COMPOUNDS
NICKEL COMPOUNDS
VANADIUM COMPOUNDS
CARBON 13
CATIONS
CESIUM COMPOUNDS
EUTECTICS
LIGANDS
LITHIUM COMPOUNDS
MOLTEN SALTS
POTASSIUM COMPOUNDS
SODIUM COMPOUNDS
SPECTROSCOPY
THIOCYANATES
ALKALI METAL COMPOUNDS
ANTITHYROID DRUGS
CARBON ISOTOPES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CHARGED PARTICLES
DRUGS
EVEN-ODD NUCLEI
HORMONE ANTAGONISTS
IONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SALTS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties