Mossbauer effect studies of intercalation compounds. [Gamma radiation]

Journal Article · Thu Jul 01 04:00:00 EDT 1982 · Acc. Chem. Res.; (United States)

DOI:https://doi.org/10.1021/ar00079a005· OSTI ID:6448220

Herber, R H

Chemical radiation effects from gamma radiation on the chemical and physicochemical properties of intercalation compounds is the subject of this report. This detailed study of molecular intercalation compounds by Mossbauer effect spectroscopy presents a wealth of information about such systems. The ferrocene and related intercalates in FeOCl host lattice provide the opportunity to examine the lattice dynamical behavior of the guest and the host species, independently, and thus probe the behavior of anisotropic solids at two very different points in the lattice. Such studies, combined with variable (low) temperature Fourier transform infrared studies and susceptability measurements, add very significantly to the knowledge of these types of materials. This report studies the Mossbauer effect for NbS/sub 2/ and TaS/sub 2/ intercalates and anhydrons FeCl/sub 3/, FeCl/sub 2/, and FeCl/sub 3/ graphite intercalation compounds.

• Research Organization: Rutgers Univ., New Brunswick, NJ
• OSTI ID: 6448220
• Journal Information: Acc. Chem. Res.; (United States), Journal Name: Acc. Chem. Res.; (United States) Vol. 15:7; ISSN ACHRE
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
CHALCOGENIDES
CHEMICAL RADIATION EFFECTS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
ELECTROMAGNETIC RADIATION
GAMMA RADIATION
HALIDES
HALOGEN COMPOUNDS
IONIZING RADIATIONS
IRON CHLORIDES
IRON COMPOUNDS
NIOBIUM COMPOUNDS
NIOBIUM SULFIDES
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
SPECTROSCOPY
SULFIDES
SULFUR COMPOUNDS
TANTALUM COMPOUNDS
TANTALUM SULFIDES
TRANSITION ELEMENT COMPOUNDS