Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Plastic deformation in oxide ceramics. Final report

Technical Report ·
OSTI ID:6445789
Plastic deformation in two non-stoichiometric oxide system - oxygen-rich UO/sub 2+x/ and Al-rich Mg-Al spinels, has been studied. In spinel, both stoichiometric and nonstoichiometric crystals were deformed at elevated temperatures and climb and climb-dissociation of <110> dislocation was ubiquitous. However, the marked composition-softening in this system, Al-rich crystals being much easier to deform than stoichiomeric crystals, was attributed to an intrinsic decrease of the stacking fault energy for glide dissociation with increasing Al/Mg ratio. In UO/sub 2+x/, the effects of O/U ratio on single crystals oriented either to suppress or promote (100)<110> slip are described. Either (111)<110> or (100)<110> slip can occur; the former is favored at low temperatures and high O/U ratios. The critical resolved shear stress for (111) slip decreases with increasing O/U ratio, while that for (100) slip is nearly constant with O/U ratio. Defect complexes are present in such oxygen-rich crystals and may re-orient in the stress fields of moving dislocations. This and their possible role in scavenging other impurity defects are believed to be involved in the variation of flow stress with O/U ratio.
Research Organization:
Case Western Reserve Univ., Cleveland, OH (USA). Dept. of Metallurgy and Materials Science
DOE Contract Number:
AC02-77ER04217
OSTI ID:
6445789
Report Number(s):
DOE/ER/04217-7; COO-4217-7; ON: DE83011047
Country of Publication:
United States
Language:
English