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U.S. Department of Energy
Office of Scientific and Technical Information

Method of increasing the oil yield from hydrogenation of coal

Patent ·
OSTI ID:6440070
The overall yield from hydrogenation of coal is increased by following the method of the present invention according to which additional amounts of oil are released from the separated residue obtained in a vacuum distillation operation following the initial coal hydrogenation, in that a light oil fraction obtained during the initial coal hydrogenation and having a boiling point in the range between 35/sup 0/ and 200/sup 0/ C is added to the residue to act as a solvent therefor, whereupon the solution is hydrogenated at a temperature in the range between 350/sup 0/ and 450/sup 0/ C under a hydrogen pressure of 300 to 400 bar for 0.5 to 2 hours. The solvent advantageously includes alkanes, cycloalkanes, aromatics, phenols or mixtures thereof having their boiling points within the above range. A catalyst selected from the series of transition metals may be added to further increase the oil yield from the hydrogenation of the residue.
Assignee:
Bergwerksverband GmbH (Germany, Federal Republic Of)
Patent Number(s):
US 4464245
OSTI ID:
6440070
Country of Publication:
United States
Language:
English