ESR study of the magnetic behavior of Mn sub 2 P sub 2 S sub 6 intercalation compounds

Journal Article · Thu May 03 04:00:00 EDT 1990 · Journal of Physical Chemistry; (USA)

DOI:https://doi.org/10.1021/j100372a086· OSTI ID:6439656

Kim, K; Cleary, D A ^[1]

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1. Washington State Univ., Pullman (USA)

The ESR spectra of Mn{sub 2}P{sub 2}S{sub 6} and several intercalation compounds of Mn{sub 2}P{sub 2}S{sub 6} are reported. The temperature dependence of the ESR line width in the case of pure Mn{sub 2}P{sub 2}S{sub 6} is consistent with antiferromagnetic ordering of Mn{sub 2}P{sub 2}S{sub 6} below 78 K. The behavior of the ESR spectrum for ammonia and pyridine intercalation compounds of Mn{sub 2}P{sub 2}S{sub 6} suggests that these materials also order antiferromagnetically but at much lower temperatures than pure Mn{sub 2}P{sub 2}S{sub 6} (11 and 36 K compared to 78 K). Cobaltocene-intercalated Mn{sub 2}P{sub 2}S{sub 6} appears to order ferromagnetically below 50 K.

• OSTI ID: 6439656
• Journal Information: Journal of Physical Chemistry; (USA), Journal Name: Journal of Physical Chemistry; (USA) Vol. 94:9; ISSN 0022-3654; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHALCOGENIDES
DATA
DATA ANALYSIS
ELECTRON SPIN RESONANCE
ELEMENTS
EXPERIMENTAL DATA
INFORMATION
MAGNETIC PROPERTIES
MAGNETIC RESONANCE
MANGANESE
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
NONMETALS
NUMERICAL DATA
PHOSPHORUS
PHYSICAL PROPERTIES
RESONANCE
SULFUR
TRANSITION ELEMENTS