Preparation of Yb(N(SiMe/sub 3/)/sub 2/)/sub 2/(AiMe/sub 3/)/sub 2/. Complex with four Yb-Me-Al interactions
Journal Article
·
· Organometallics; (United States)
Trimethylaluminum reacts with base-free ytterbium bis(bis(trimethylsilyl)amide) to give Yb(N-(SiMe/sub 3/)/sub 2/)/sub 2/(AlMe/sub 3/)/sub 2/. The x-ray crystal structure provides evidence for four Yb-Me-Al and two Yb-Me-Si bridging interactions.
- Research Organization:
- Univ. of California, Berkeley
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 6436909
- Journal Information:
- Organometallics; (United States), Journal Name: Organometallics; (United States) Vol. 4:1; ISSN ORGND
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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Tue Mar 15 23:00:00 EST 1983
· Inorg. Chem.; (United States)
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OSTI ID:6263668
A monomeric solvent-free bent lanthanide dialkyl and a lanthanide analogue of a Grignard reagent. Crystal structures of Yb[l brace]C(SiMe[sub 3])[sub 3][r brace][sub 2] and [Yb[l brace]C(SiMe[sub 3])[sub 3][r brace]I[center dot]OEt[sub 2]][sub 2]
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Tue Dec 27 23:00:00 EST 1994
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OSTI ID:6604651
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ALUMINIUM COMPOUNDS
AZIDES
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
HYDROCARBONS
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RARE EARTH COMPOUNDS
SILICON COMPOUNDS
SYNTHESIS
YTTERBIUM COMPOUNDS
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
ALUMINIUM COMPOUNDS
AZIDES
CHEMICAL PREPARATION
CRYSTAL STRUCTURE
HYDROCARBONS
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
RARE EARTH COMPOUNDS
SILICON COMPOUNDS
SYNTHESIS
YTTERBIUM COMPOUNDS