Gum and deposit formation from jet turbine and diesel fuels at 100/sup 0/C

Journal Article · Sat Jan 31 23:00:00 EST 1987 · Ind. Eng. Chem. Res.; (United States)

DOI:https://doi.org/10.1021/ie00062a008· OSTI ID:6432674

Mayo, F R; Lan, B Y

Rates of oxidation and gum formation for six hydrocarbons, three jet turbine fuels and three diesel fuels have been measured at 100/sup 0/C in the presence of t-Bu/sub 2/O/sub 2/ as initiator. Four of the six fuels oxidize faster at 100/sup 0/C than in previous work at 130/sup 0/C without initiator. For any single substrate, the amount of gum produced for the oxygen absorbed is similar at 100 and 130/sup 0/C, even with large changes in rates and t-Bu/sub 2/O/sub 2/ concentrations. In general, the pure hydrocarbons have long kinetic chains and give good yields of hydroperoxides.

• Research Organization: SRI International, Menlo Park, CA 94025
• OSTI ID: 6432674
• Journal Information: Ind. Eng. Chem. Res.; (United States), Journal Name: Ind. Eng. Chem. Res.; (United States) Vol. 26:2; ISSN IECRE
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020500 -- Petroleum-- Products & By-Products
023000* -- Petroleum-- Properties & Composition
ADDITIVES
ADSORPTION
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CORROSIVE EFFECTS
DEPOSITS
DIESEL FUELS
ELEMENTS
FUEL ADDITIVES
FUELS
GUMS
HIGH TEMPERATURE
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN PEROXIDE
JET ENGINE FUELS
KINETICS
MEDIUM TEMPERATURE
NONMETALS
ORGANIC COMPOUNDS
OXIDATION
OXYGEN
OXYGEN COMPOUNDS
PEROXIDES
PETROLEUM PRODUCTS
QUANTITY RATIO
REACTION KINETICS
SCALING
SORPTION
SUBSTRATES
YIELDS