Cyclopentadienyl ring methylation and its effect on Si-H bond activation in (. eta. sup 5 -C sub 5 H sub 5 minus n (CH sub f3 ) sub n )Mn(CO) sub 2 HSiH(C sub 6 H sub 5 ) sub 2 (n = 0,1,5) complexes
- Univ. of Arizona, Tucson (USA)
The He I photoelectron spectra of ({eta}{sup 5}-C{sub 5}H{sub 5})Mn(CO){sub 2}HSiHPh{sub 2}, ({eta}{sup 5}-C{sub 5}H{sub 4}CH{sub 3})Mn(CO){sub 2}HSiHPh{sub 2} and ({eta}{sup 5}-C{sub 5}(CH{sub 3}){sub 5})Mn(CO){sub 2}HSiHPh{sub 2} (Ph is C{sub 6}H{sub 5}) are compared to observe the effect of cyclopentadienyl ring methylation on the extent of Si-H bond interaction with the transition metal in these complexes.
- DOE Contract Number:
- FG02-86ER13501
- OSTI ID:
- 6429070
- Journal Information:
- Organometallics; (USA), Journal Name: Organometallics; (USA) Vol. 9:5; ISSN 0276-7333; ISSN ORGND
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CHEMICAL ACTIVATION
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
CYCLOPENTADIENE
DATA
DATA ANALYSIS
DIENES
ELECTRON SPECTROSCOPY
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
METHYLATION
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
POLYENES
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
ALKENES
CHEMICAL ACTIVATION
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
CYCLOPENTADIENE
DATA
DATA ANALYSIS
DIENES
ELECTRON SPECTROSCOPY
EXPERIMENTAL DATA
HYDROCARBONS
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
METHYLATION
NUMERICAL DATA
ORGANIC COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
POLYENES
SPECTROSCOPY
TRANSITION ELEMENT COMPLEXES