Structure-property relations of Kevlar 49 fibers

Conference · Sun Mar 01 00:00:00 EST 1981

OSTI ID:6428897

Pruneda, C O; Steele, W J; Kershaw, R P; Morgan, R J

The relation between the physical structure and deformation and failure processes of Kevlar fibers is presented. The fiber fabrication processes that affect the critical structural parameters controlling deformation and failure are considered. The deformation and failure processes are discussed in the light of fracture topography studies of epoxy composite strands and non-etched and HCl-etched bare yarns together with deformation studies of bare yarns deformed directly in the optical microscope. A physical model is suggested for Kelvar 49 in which there is an amorphous skin and crystalline core. The core consists of periodic transverse defect planes spaced about 200 nm along the fiber. Chain ends are assumed to cluster within the vicinity of these planes. The non-crystalline skin in which the chain ends are arranged essentially randomly relative to one another does not contain such transverse weak planes.

• Research Organization: Lawrence Livermore National Lab., CA (USA)
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 6428897
• Report Number(s): UCRL-85744; CONF-810813-3
• Resource Relation: Conference: National American Chemical Society summer meeting, New York, NY, USA, 23 Aug 1981
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
ARAMIDS
DEFORMATION
FAILURES
FABRICATION
FIBERS
FRACTURES
OPTICAL MICROSCOPY
MATERIALS
MICROSCOPY
PETROCHEMICALS
PETROLEUM PRODUCTS
PLASTICS
SYNTHETIC MATERIALS
360402* - Polymers & Plastics- Structure & Phase Studies- (-1987)
360403 - Materials- Polymers & Plastics- Mechanical Properties- (-1987)