Measurement of the intracrystalline self-diffusion of xenon in zeolites by the NMR pulsed field gradient technique

Journal Article · Wed Mar 14 04:00:00 EST 1990 · Journal of the American Chemical Society; (USA)

DOI:https://doi.org/10.1021/ja00162a019· OSTI ID:6428858

Heink, W; Kaerger, J; Pfeifer, H; Stallmach, F ^[1]

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1. Karl-Marx-Universitaet, Leipzig (East Germany)

With use of {sup 129}Xe NMR, the NMR pulsed field gradient technique is applied to study the self-diffusion of xenon adsorbed on zeolites NaX, NaCaA, and ZSM-5. In their dependence on both the type of adsorbent and the sorbate concentration, the self-diffusion coefficients are found to follow the same patterns as previously determined for methane by {sup 1}H NMR. For NaCaA, the comparison of the present results with literature data reveals large discrepancies, while recent computer simulations of xenon self-diffusion in ZSM-5 are found to be in reasonable agreement.

• OSTI ID: 6428858
• Journal Information: Journal of the American Chemical Society; (USA), Journal Name: Journal of the American Chemical Society; (USA) Vol. 112:6; ISSN 0002-7863; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
DATA
DATA ANALYSIS
DAYS LIVING RADIOISOTOPES
DIFFUSION
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
INFORMATION
INORGANIC ION EXCHANGERS
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
ION EXCHANGE MATERIALS
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
MAGNETIC RESONANCE
MATERIALS
MEASURING INSTRUMENTS
MEASURING METHODS
MINERALS
NUCLEAR MAGNETIC RESONANCE
NUCLEI
NUMERICAL DATA
RADIOISOTOPES
RESONANCE
SELF-DIFFUSION
STABLE ISOTOPES
XENON 129
XENON ISOTOPES
ZEOLITES