Participation of the anthracene/trans,trans-2,4-hexadiene exciplex in anthracene photodimerization
Conference
·
· Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States)
OSTI ID:6428731
Observations with the anthracene(A)/trans,trans-2,3-hexadiene(D) system revealing diene enhancement of the photodimerization in the parent hydrocarbon were previously reported. There was disagreement on the dimerization mechanism. Detailed observations are reported which firmly establishes a mechanism involving reaction of ground state anthracene with an exciplex /sup 1/(AD) as the mechanism for enhanced photodimerization in this system. (JSR)
- Research Organization:
- Florida State Univ., Tallahassee
- OSTI ID:
- 6428731
- Report Number(s):
- CONF-790415-P1
- Conference Information:
- Journal Name: Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States) Journal Volume: 24:1
- Country of Publication:
- United States
- Language:
- English
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