Applications of ZVMo NMR spectroscopy. 17. ZVMo and UN relaxation time measurements confirming that (Mo(CN)8)U is dodecahedral in aqueous solution
Journal Article
·
· Inorg. Chem.; (United States)
Variable-temperature NMR line width measurements of ZVMo and UN in aqueous solutions of K4(Mo(CN)8) x 2H2O indicate that the stereochemistry of the (Mo(CN)8)U ion in solution is dodecahedral. A value for the ZVMo quadrupole coupling constant of 3.61 MHz is obtained. 27 references, 1 figure, 1 table.
- Research Organization:
- La Trobe Univ., Bundoora, Australia
- OSTI ID:
- 6425595
- Journal Information:
- Inorg. Chem.; (United States), Vol. 26:13
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MOLYBDENUM 95
RELAXATION TIME
MOLYBDENUM COMPOUNDS
NMR SPECTRA
NITROGEN 14
EXPERIMENTAL DATA
TEMPERATURE DEPENDENCE
DATA
EVEN-ODD NUCLEI
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOTOPES
LIGHT NUCLEI
MOLYBDENUM ISOTOPES
NITROGEN ISOTOPES
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
REFRACTORY METAL COMPOUNDS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MOLYBDENUM 95
RELAXATION TIME
MOLYBDENUM COMPOUNDS
NMR SPECTRA
NITROGEN 14
EXPERIMENTAL DATA
TEMPERATURE DEPENDENCE
DATA
EVEN-ODD NUCLEI
INFORMATION
INTERMEDIATE MASS NUCLEI
ISOTOPES
LIGHT NUCLEI
MOLYBDENUM ISOTOPES
NITROGEN ISOTOPES
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
REFRACTORY METAL COMPOUNDS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation