Preliminary results from a quasi-classical trajectory analysis of the H + O/sub 2/. -->. OH + O reaction
Technical Report
·
OSTI ID:6425565
This report compares the results of a quasi-classical analysis with experimental results for the rate coefficient of the H + O/sub 2/ ..-->.. OH + O reaction in the high temperature (1250 to 2500 K) regime. The trajectory results are in good agreement with Schott's experiments but are not consistent with the Leeds recommendation in this temperature range. It is deduced that vibrational nonequilibrium effects are not likely to be responsible for the non-Arrhenius temperature dependence of this reaction.
- Research Organization:
- Sandia Labs., Livermore, CA (USA)
- DOE Contract Number:
- EY-76-C-04-0789
- OSTI ID:
- 6425565
- Report Number(s):
- SAND-79-8205
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400800* -- Combustion
Pyrolysis
& High-Temperature Chemistry
ATOM COLLISIONS
ATOM-MOLECULE COLLISIONS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COLLISIONS
COMBUSTION
COMPARATIVE EVALUATIONS
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROGEN
KINETICS
MOLECULE COLLISIONS
NONMETALS
OXIDATION
OXYGEN
REACTION KINETICS
THERMOCHEMICAL PROCESSES
VERY HIGH TEMPERATURE
400800* -- Combustion
Pyrolysis
& High-Temperature Chemistry
ATOM COLLISIONS
ATOM-MOLECULE COLLISIONS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COLLISIONS
COMBUSTION
COMPARATIVE EVALUATIONS
CRYOGENIC FLUIDS
ELEMENTS
FLUIDS
HYDROGEN
KINETICS
MOLECULE COLLISIONS
NONMETALS
OXIDATION
OXYGEN
REACTION KINETICS
THERMOCHEMICAL PROCESSES
VERY HIGH TEMPERATURE