Magnetic properties of M(VOPO{sub 4}){sub 2}{center_dot}4H{sub 2}O (M = Co(II), Ni(II)), layered compounds containing distinct magnetic linear trimers
Journal Article
·
· Journal of Solid State Chemistry
- Academia Sinica, Taipei (Taiwan, Province of China). Inst. of Chemistry
Layered vanadyl phosphate, VOPO{sub 4}{center_dot}2H{sub 2}O, is well known for its catalytic activity. A magnetic study has been carried out on the transition metal intercalated vanadyl phosphates M(VOPO{sub 4}){sub 2}{center_dot}4H{sub 2}O (M = Co{sup 2+}, Ni{sup 2+}), which contain linear trimers of V{double_bond}O{single_bond}M{single_bond}O{double_bond}V between the layers. Ferromagnetic interactions have been found to be mediated through these linear trimers.
- OSTI ID:
- 642151
- Journal Information:
- Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Journal Issue: 1 Vol. 137; ISSN 0022-4596; ISSN JSSCBI
- Country of Publication:
- United States
- Language:
- English
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