Role of intramolecular Pd. Ph coordination in the stabilization of the binuclear complex Pd/sub 2/(PPh/sub 3/)/sub 2/
Journal Article
·
· Sov. J. Coordinat. Chem.; (United States)
OSTI ID:6419468
A CNDO calculation of the electronic structure of model structures of Pd/sub 2/(PPh/sub 3/)/sub 2/ has been performed for the purpose of studying the role of the intramolecular Pd...Ph coordination in the stabilization of the binuclear complex Pd/sub 2/(PPh/sub 3/)/sub 2/. The electronic factor determining the possibility of Pd...Ph coordination is the donor-acceptor interaction of the weakly filled 5s and 5p AO's of Pd with the filled orbitals of the aromatic rings, which results in lowering of the coordinative unsaturation of the Pd atoms in Pd/sub 2/L/sub 2/.
- OSTI ID:
- 6419468
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 10:10; ISSN SJCCD
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and reactivity of Ph/sub 2/PCH/sub 2/PPh/sub 2/- (dppm-) stabilized Pd-Co and Pd-Pt-Co clusters. Effect of platinum versus palladium on the neighboring palladium center
Novel reactions of metal-metal bonds. Addition of sulfur dioxide and sulfur to Pd/sub 2/(Ph/sub 2/PCH/sub 2/PPh/sub 2/)/sub 2/Cl/sub 2/ and the oxidation of coordinated sulfide
Investigation of the reaction of Pd(acac)/sub 2/ x PPh/sub 3/ with molecular hydrogen
Journal Article
·
Wed Apr 20 00:00:00 EDT 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5708148
Novel reactions of metal-metal bonds. Addition of sulfur dioxide and sulfur to Pd/sub 2/(Ph/sub 2/PCH/sub 2/PPh/sub 2/)/sub 2/Cl/sub 2/ and the oxidation of coordinated sulfide
Journal Article
·
Wed Oct 31 23:00:00 EST 1979
· Inorg. Chem.; (United States)
·
OSTI ID:5549979
Investigation of the reaction of Pd(acac)/sub 2/ x PPh/sub 3/ with molecular hydrogen
Journal Article
·
Thu Mar 31 23:00:00 EST 1988
· Sov. J. Coordinat. Chem.; (United States)
·
OSTI ID:7006197
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BINDING ENERGY
CHEMICAL BONDS
COMPLEXES
COMPLEXOMETRY
CONFIGURATION INTERACTION
COORDINATION VALENCES
EFFECTIVE CHARGE
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ENERGY LEVELS
FERMIONS
LCAO METHOD
LEPTONS
LIGANDS
MOLECULAR ORBITAL METHOD
MOLECULAR STRUCTURE
PALLADIUM COMPLEXES
PHOSPHINES
PHOSPHORUS COMPOUNDS
STABILIZATION
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPLEXES
VALENCE
400201* -- Chemical & Physicochemical Properties
BINDING ENERGY
CHEMICAL BONDS
COMPLEXES
COMPLEXOMETRY
CONFIGURATION INTERACTION
COORDINATION VALENCES
EFFECTIVE CHARGE
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ENERGY LEVELS
FERMIONS
LCAO METHOD
LEPTONS
LIGANDS
MOLECULAR ORBITAL METHOD
MOLECULAR STRUCTURE
PALLADIUM COMPLEXES
PHOSPHINES
PHOSPHORUS COMPOUNDS
STABILIZATION
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPLEXES
VALENCE