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Mechanism of the oxidation of acetylacetone by hydrogen peroxide, catalyzed by Mo(VI) complexes (in Russian)

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00956580· OSTI ID:6417398
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Oxidation of the acetylacetonate ion in the coordination sphere of molybdenum(VI) by hydrogen peroxide proceeds without the participation of paramagnetic particles, recordable by steady-state ESR methods. It was established by the PMR method that the oxidation of 2,4-pentanedione by hydrogen peroxide in the presence of sodium molybdate proceeds through intermediate formation of the complex of Mo(VI) with 3,3-dihydroxy-2,4-pentanedione. A complex of Mo(VI) with 3,3-dihydroxy-2,4-pentanedione was produced for the first time.
Research Organization:
N. S. Kurnakov Institute of General and Inorganic Chemistry, Moscow, USSR
OSTI ID:
6417398
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:6; ISSN BACCA
Country of Publication:
United States
Language:
Russian

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETYLACETONE
ALDEHYDES
ALKALI METAL COMPOUNDS
CARBOXYLIC ACIDS
CATALYTIC EFFECTS
CHALCOGENIDES
CHELATING AGENTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
ELECTRON SPIN RESONANCE
FORMALDEHYDE
FORMIC ACID
HYDROGEN COMPOUNDS
HYDROGEN PEROXIDE
INFRARED SPECTRA
KETONES
KINETICS
LIGANDS
MAGNETIC RESONANCE
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
MONOCARBOXYLIC ACIDS
NMR SPECTRA
ORGANIC ACIDS
ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
REAGENTS
REFRACTORY METAL COMPOUNDS
RESONANCE
SODIUM COMPOUNDS
SODIUM OXIDES
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS