Technical and economic feasibility of sulfur trioxide retorting

Conference · Tue Oct 01 04:00:00 EDT 1985

OSTI ID:6417121

Johnson, L A; Wing, E E

A laboratory evaluation of oil shale retorting using sulfur trioxide injection has shown that sufficient heat is generated to retort oil shale. But the direct reaction of sulfur trioxide and oil shale results in large oil yield losses. A screening evaluation of the economic feasibility for sulfur trioxide retorting indicated that the large oil yield losses increase shale oil production costs relative to conventional retorting processes. Sulfur trioxide may be an economical alternative to air for oxidation of retorted shale in retorting processes using solid heat carriers. In this case, the shale is heated largely by the exothermic reaction of sulfur trioxide with the mineral carbonates in the shale. The hot retorted shale can be mixed with raw shale to isolate the oil and gas production from the sulfur trioxide reactions. A screening evaluation of this alternative use for sulfur trioxide indicates that the by-product credits for high Btu off-gas and CO/sub 2/ may offset the additional production costs for the sulfur trioxide. 11 refs., 7 figs., 12 tabs.

• Research Organization: Western Research Inst., Laramie, WY (USA)
• DOE Contract Number: FC21-83FE60177
• OSTI ID: 6417121
• Report Number(s): DOE/FE/60177-1975; ON: DE86003738
• Country of Publication: United States
• Language: English

Related Subjects

04 OIL SHALES AND TAR SANDS
040402* -- Oil Shales & Tar Sands-- Surface Methods
BITUMINOUS MATERIALS
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON OXIDES
CARBONACEOUS MATERIALS
CHALCOGENIDES
CHEMICAL REACTIONS
DECOMPOSITION
ENERGY SOURCES
FLUIDS
FOSSIL FUELS
FUELS
GASES
HEATING
MATERIALS
MINERAL OILS
OIL SHALES
OIL YIELDS
OILS
ORGANIC COMPOUNDS
OTHER ORGANIC COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
RETORTING
SHALE GAS
SHALE OIL
SULFUR COMPOUNDS
SULFUR OXIDES
SULFUR TRIOXIDE
YIELDS