Infrared and Raman spectra of potassium pentacyanonitrosylmanganate(I) dihydrate

Journal Article · Wed Apr 01 04:00:00 EST 1987 · J. Crystallogr. Spectrosc. Res.; (United States)

DOI:https://doi.org/10.1007/BF01160906· OSTI ID:6414719

Soria, D B; Amalvy, J I; Aymonino, P J

The infrared spectra of polycrystalline K/sub 3/(Mn(CN)/sub 5/NO) x 2H/sub 2/O at different degrees of deuteration were recorded between 4000 and 200 cm/sup -1/, both at room and low temperature. The room-temperature Raman spectrum of the isotopically normal powder was also obtained. The observed bands were assigned to the internal vibrational modes of the (Mn(CN)/sub 5/NO)/sup 3 -/ ion and to the internal and vibrational modes of water of hydration. In accordance with X-ray diffraction studies, the spectra showed the existence of two crystallographically distinct types of water molecules located in different sets of sites of C/sub 1/ symmetry.

• Research Organization: Universidad Nacional de La Plata, Argentina
• OSTI ID: 6414719
• Journal Information: J. Crystallogr. Spectrosc. Res.; (United States), Journal Name: J. Crystallogr. Spectrosc. Res.; (United States) Vol. 17:2; ISSN JCRED
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKALI METAL COMPOUNDS
BOND LENGTHS
CHEMICAL BONDS
CHEMICAL REACTIONS
COHERENT SCATTERING
COMPLEXES
CRYSTAL STRUCTURE
CRYSTALS
DEUTERATION
DEUTERIUM COMPOUNDS
DIFFRACTION
DIMENSIONS
ENERGY LEVELS
EVEN-EVEN NUCLEI
EXCITED STATES
HYDRATES
HYDRATION
HYDROGEN COMPOUNDS
HYPERFINE STRUCTURE
INFRARED SPECTRA
ISOTOPES
LENGTH
LIGHT NUCLEI
LINE WIDTHS
MANGANESE COMPLEXES
NITROGEN 14
NITROGEN 15
NITROGEN ISOTOPES
NUCLEI
ODD-EVEN NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN 18
OXYGEN ISOTOPES
POLYCRYSTALS
POTASSIUM COMPOUNDS
RAMAN SPECTRA
SCATTERING
SOLVATION
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPLEXES
VIBRATIONAL STATES
X-RAY DIFFRACTION