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U.S. Department of Energy
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Characterization of solid constituents in blackwater effluents from coal preparation plants

Technical Report ·
OSTI ID:6414423
Characterization of the fine solid material in the primary effluent from coal preparation plants provides the basis for a better understanding of the problems associated with treating ''blackwater.'' The present study was made to obtain a comprehensive characterization of the blackwater solids from coal preparation plants. The suspended solids from thirteen blackwater samples, representative of the major United States coal seams where wet preparation methods are used, were characterized by mineralogical content, particle size distribution, and surface properties. The conclusions from this work are as follows: blackwater solids consist of two types of material--carbonaceous and mineral--of distinctly different chemical and physical properties. Based on mineralogical similarities, the samples were divided into two groups: those from the Eastern half of the United States and those from the Western half. The mineralogical content of the eleven Eastern samples was similar, while the two Western samples were different from the Eastern ones, as well as as from each other. Additional clean coal may be recovered from current blackwater discharges from preparation plants by a more extensive use of the flotation process. The average ash content of the carbonaceous fraction removed by froth flotation was 11%, as compared to an average of 41% ash in the as received blackwater samples. The mineral fraction of the blackwater solids from Eastern and Midwestern coal fields contains largely illitic clays together with lesser amounts of kaolinite, quartz, calcite, chlorite, and pyrite. Minor amounts of dolomite, feldspar, rutile, or siderite were found in some of the samples.
Research Organization:
Pennsylvania State Univ., University Park (USA)
OSTI ID:
6414423
Report Number(s):
FE-9002-1; EPA-600/7-79-006
Country of Publication:
United States
Language:
English