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Title: An examination of utility emissions contributions to elevated ozone concentrations in the Chicago area

Conference ·
OSTI ID:6413636

In order to reduce the pollutant load to the atmosphere and subsequent damaging effects, Titles I and IV of the Clean Air Act Amendments of 1990 (CAAAs) require reductions in emissions of sulfur dioxide (SO[sub 2]), nitrogen oxides (NO[sub x]), and volatile organic compounds (VOCs). Title IV is aimed at reducing acidic deposition and requires utilities to reduce SO[sub 2] and NO[sub x] emissions to specified levels. As a consequence of this, many utilities will have to install SO[sub 2] and NO[sub x] control technologies. Title I is concerned with bringing regions into compliance with the National Ambient Air Quality Standards (NAAQS) for the criteria pollutants, among which is ozone (O[sub 3]). The NAAQS for O[sub 3] is 120 ppb (parts per billion by volume) hourly average concentration, not to be exceeded four times in three years. O[sub 3] is a secondary pollutant formed in the atmosphere when NO[sub x] and VOCs react together in the presence of sunlight. Utilities are a significant source of NO[sub x] and an unimportant source of VOCs. In the past, O[sub 3] control strategy has focused on reducing VOC emissions because of the possibility that reducing NO[sub x] actually might make O[sub 3] concentrations higher. However, this approach has not worked, perhaps because of underestimation of natural and manmade VOC emissions and transport of O[sub 3] from other regions. Computer modeling has shown that for many highly polluted areas massive NO[sub x] reductions may be necessary in addition to or in place of VOC controls. Utilities are a potential source of these NO[sub x] reductions.

Research Organization:
Argonne National Lab., IL (United States). Environmental Assessment and Information Sciences Div.
Sponsoring Organization:
USDOE; USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
6413636
Report Number(s):
ANL/EAIS/CP-78927; CONF-930647-2; ON: DE93012852
Resource Relation:
Conference: 86. annual meeting and exhibition of the Air and Waste Management Association, Denver, CO (United States), 13-18 Jun 1993
Country of Publication:
United States
Language:
English