Olefin oxidation by zeolite-encapsulated Mn(salen) sup + complexes under ambient conditions
Journal Article
·
· Journal of Catalysis; (USA)
- Ohio State Univ., Columbus (USA)
Zeolite-encapsulated manganese complex of the salen ligand (N,N{prime}-ethylenebis(salicylideneaminato)) was synthesized, and its catalytic activity toward various olefins was examined. Iodosylbenzene was chosen to be the terminal oxidant. Oxidation products, which included the epoxide, alcohol, and aldehyde, are formed from cyclohexene, styrene, and trans- and cis-stilbene. In comparison with catalysis by Mn(salen){sup +} complexes in solution, encapsulation lowers the rate of reaction considerably, but provides for selective oxidation based on olefin size and ability to penetrate the zeolite cages.
- OSTI ID:
- 6409753
- Journal Information:
- Journal of Catalysis; (USA), Journal Name: Journal of Catalysis; (USA) Vol. 122:2; ISSN 0021-9517; ISSN JCTLA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Specific DNA cleavage mediated by [SalenMn(III)][sup +]
Metal complex-catalyzed epoxidation of olefins by dioxygen with co-oxidation of aldehydes: A mechanistic study
Oxygen atom transfer from {mu}-Oxo-bis[1,4,8,11,15,18,22,25-octakis(trifluoromethyl)ph-thalocya ninato]diiron(III) : evidence for an Fe(IV)=O intermediate.
Journal Article
·
Thu Feb 11 23:00:00 EST 1993
· Journal of Organic Chemistry; (United States)
·
OSTI ID:6347232
Metal complex-catalyzed epoxidation of olefins by dioxygen with co-oxidation of aldehydes: A mechanistic study
Journal Article
·
Tue Feb 13 23:00:00 EST 1996
· Inorganic Chemistry
·
OSTI ID:258384
Oxygen atom transfer from {mu}-Oxo-bis[1,4,8,11,15,18,22,25-octakis(trifluoromethyl)ph-thalocya ninato]diiron(III) : evidence for an Fe(IV)=O intermediate.
Journal Article
·
Wed Dec 31 23:00:00 EST 1997
· J. Porphyrins Phthalocyanines
·
OSTI ID:938153
Related Subjects
02 PETROLEUM
020400* -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ALCOHOLS
ALDEHYDES
ALKENES
ALKYLATED AROMATICS
AROMATICS
CATALYST SUPPORTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
ENCAPSULATION
EPOXIDES
HEXENES
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
LIGANDS
MANGANESE COMPLEXES
MATERIALS
MINERALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
REACTION KINETICS
STILBENE
STYRENE
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
ZEOLITES
020400* -- Petroleum-- Processing
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
ALCOHOLS
ALDEHYDES
ALKENES
ALKYLATED AROMATICS
AROMATICS
CATALYST SUPPORTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
ENCAPSULATION
EPOXIDES
HEXENES
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
LIGANDS
MANGANESE COMPLEXES
MATERIALS
MINERALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
REACTION KINETICS
STILBENE
STYRENE
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
ZEOLITES