Electrochemical cell including a solid electrolyte made from a cation conductive vitreous compound

Patent · Tue Apr 24 04:00:00 EST 1984

OSTI ID:6408668

Duchange, J P; Gabano, J P

An electrochemical cell having a lithium based negative active material, an electrolyte in the form of a vitreous cation conductive compound having a formula: aP/sub 2/S/sub 5/, bLi/sub 2/S, cLiX, where X stands for chlorine, bromine or iodine, and a, b, and c are numbers chosen in such a manner that b/(a+b) lies in the range 0.61 to 0.70 and c/(a+b+c) is less than or equal to the maximum solubility in the vitreous phase of LiX in the compound aP/sub 2/S/sub 5/, bLi/sub 2/S, and a positive active material in the form of a compressed powder with particles of the electrolyte dispersed throughout said positive active material. The positive active material is chosen from the group constituted by: (CH /SUB x/ ; Cu /SUB d/ O(PO/sub 4/)/sub 2/; V/sub 6/O/sub 13/; V/sub 2/S/sub 5/; MoS/sub 3/; CuS; S; CuO; Cu/sub 3/B/sub 2/O/sub 6/; FeS/sub 2/; Pb/sub 3/O/sub 4/; Bi/sub 2/O/sub 3/; PbO; BiO(CrO/sub 4/)/sub 2/; AgBi(CrO/sub 4/)/sub 2/; I/sub 2/; MoO/sub 3/; WO/sub 3/; TiS/sub 2/; NiPS/sub 3/; copper bismuthate; and lead bismuthate.

• Assignee: Societe Anonyme dite GIPELEC (France)
• Patent Number(s): US 4444857
• OSTI ID: 6408668
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
250901* -- Energy Storage-- Batteries-- Design & Development
ALKALI METAL COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CHALCOGENIDES
CHEMICAL COMPOSITION
CHLORIDES
CHLORINE COMPOUNDS
DESIGN
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTROLYTES
HALIDES
HALOGEN COMPOUNDS
INORGANIC PHOSPHORS
IODIDES
IODINE COMPOUNDS
LITHIUM BROMIDES
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM IODIDES
LITHIUM SULFIDES
LITHIUM-CHLORINE BATTERIES
METAL-GAS BATTERIES
PHOSPHORS
PHOSPHORUS COMPOUNDS
PHOSPHORUS SULFIDES
SOLID ELECTROLYTES
SULFIDES
SULFUR COMPOUNDS