Statistical treatment of EPR data: The spectrum of IO/sub 2/ in KIO/sub 2/F/sub 2/ single crystals

Journal Article · Fri May 15 00:00:00 EDT 1981 · J. Chem. Phys.; (United States)

OSTI ID:6399442

Atherton, N M; Morton, J R; Preston, K F; Strach, S J

The EPR spctrum in g-irradiated KIO/sub 2/F/sub 2/ crystals has been reinvestigated. Originally thought to be due to IO/sub 2/F/sup -/, the spectrum has been reanalyzed and reassigned to the radical IO/sub 2/. Improved principal values for the g factor and the /sup 127/I hyperfine and quadrupole interactions were obtained by the statistical technique of minimizing x/sup 2/ for measurements made with H/sub 0/ parallel to the crystal axes.

• Research Organization: Division of Chemistry, National Research Council of Canada, Ottawa K1A 0R9, Canada
• OSTI ID: 6399442
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 74:10; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ALKALI METAL COMPOUNDS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CRYSTALS
DECOMPOSITION
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
FLUORIDES
FLUORINE COMPOUNDS
GAMMA RADIATION
HALIDES
HALOGEN COMPOUNDS
HYPERFINE STRUCTURE
IODATES
IODINE COMPOUNDS
IONIZING RADIATIONS
MAGNETIC RESONANCE
MONOCRYSTALS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADICALS
RADIOLYSIS
RESONANCE