Propensity rules in rotationally inelastic polar molecule collisions involving /sup 2/. sigma. /sup +/ molecules: CaCl(X /sup 2/. sigma. /sup +/)--CH/sub 3/Cl

Journal Article · Mon Oct 01 00:00:00 EDT 1984 · J. Chem. Phys.; (United States)

OSTI ID:6398342

Bullman, S J; Dagdigian, P J

Integral state-resolved cross sections are presented for the scattering of CaCl with CH/sub 3/Cl target. This particular system was chosen so that the potential could be represented as the long-range dipole-dipole interaction. Fluorescence was observed by using a single mode dye laser as excitation source. Rotationally inelastic cross sections were determined from measurement of line intensities as a function of scattering gas pressure. (AIP)

• Research Organization: Department of Chemistry, The Johns Hopkins University, Baltimore, Maryland 21218
• OSTI ID: 6398342
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 81:7; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

640304* -- Atomic
Molecular & Chemical Physics-- Collision Phenomena
74 ATOMIC AND MOLECULAR PHYSICS
ALKALINE EARTH METAL COMPOUNDS
BEAMS
CALCIUM CHLORIDES
CALCIUM COMPOUNDS
CALCIUM HALIDES
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
COLLISIONS
CROSS SECTIONS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
METHYL CHLORIDE
MOLECULAR BEAMS
MOLECULE COLLISIONS
MOLECULE-MOLECULE COLLISIONS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ROTATIONAL STATES