Analysis of metalloporphyrins in petroleum using tandem mass spectrometry

Journal Article · Tue Dec 31 23:00:00 EST 1985 · Fuel Sci. Technol. Int.; (United States)

DOI:https://doi.org/10.1080/08843758608915836· OSTI ID:6390339

Brodbelt, J S; Cooks, R G; Wood, K V; Jackson, T J

Vanadyl deoxophylloerythroetioporphyrins (DPEP) and vanadyl etioporphyrins (ETIO) have been identified in Gato Ridge and Boscan petroleum samples using a combination of isobutane chemical ionization and tandem mass spectrometry. In addition, particular porphyrins such as the C/sub 30/ vanadyl DPEP and ETIO species were identified in a crude oil containing approximately 500 ppm total porphyrins, with only minimal sample clean-up.

• Research Organization: Dept. of Chemistry, Purdue Univ., West Lafayette, IN 47907
• OSTI ID: 6390339
• Journal Information: Fuel Sci. Technol. Int.; (United States), Journal Name: Fuel Sci. Technol. Int.; (United States) Vol. 4:6; ISSN FSCTE
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
023000* -- Petroleum-- Properties & Composition
2-METHYLPROPANE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102 -- Chemical & Spectral Procedures
ALKANES
CARBOXYLIC ACIDS
CHEMICAL ANALYSIS
ENERGY SOURCES
FOSSIL FUELS
FUELS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
IONIZATION
MASS SPECTROSCOPY
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PETROLEUM
PORPHYRINS
QUANTITY RATIO
SPECTROSCOPY