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Synthesis of 1-alkylthio-3-allylthio-1-propenes by the reaction of dialllyl disulfide with allyl halides in the alkali-metal hydroxide-DMSO superbasic system

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6388212
; ; ; ; ;
The reaction of diallyl disulfide with alkyl halides in the alkali-metal hydroxide-DMSO superbasic system leads to the formation of 1-alkylthio-3-allylthio-1-propenes and 1,3-di(alkylthio)propenes. The effects of the structure of the alkyl halides, the nature of the alkali-metal cations, the halogen, and the reaction conditions on the yield and ratio of the products were investigated.
Research Organization:
Irkutsk Institute of Organic Chemistry, USSR
OSTI ID:
6388212
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:5; ISSN JOCYA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
ALKENES
BROMINATED ALIPHATIC HYDROCARBONS
CARBON 13
CARBON ISOTOPES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
COMPARATIVE EVALUATIONS
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DISULFIDES
DMSO
ENERGY
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXIDES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
IODINATED ALIPHATIC HYDROCARBONS
IONIZATION
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
KINETICS
LIGHT NUCLEI
LITHIUM COMPOUNDS
LITHIUM HYDROXIDES
MASS SPECTRA
METHYL IODIDE
NMR SPECTRA
NUCLEI
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
POTASSIUM HYDROXIDES
REACTION KINETICS
SODIUM COMPOUNDS
SODIUM HYDROXIDES
SOLVENT PROPERTIES
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SULFOXIDES
SYNTHESIS
YIELDS