Synthesis of 1-alkylthio-3-allylthio-1-propenes by the reaction of dialllyl disulfide with allyl halides in the alkali-metal hydroxide-DMSO superbasic system

Journal Article · Fri Oct 10 00:00:00 EDT 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6388212

Amosova, S V; Nosyreva, V V; Musorin, G K; Sigalov, M V; Sinegovskaya, L M; Trofimov, B A

The reaction of diallyl disulfide with alkyl halides in the alkali-metal hydroxide-DMSO superbasic system leads to the formation of 1-alkylthio-3-allylthio-1-propenes and 1,3-di(alkylthio)propenes. The effects of the structure of the alkyl halides, the nature of the alkali-metal cations, the halogen, and the reaction conditions on the yield and ratio of the products were investigated.

• Research Organization: Irkutsk Institute of Organic Chemistry, USSR
• OSTI ID: 6388212
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 22:5; Other Information: Translated from Zh. Org. Khim.; 22: No.5, 957-964(May 1986)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ALKENES
NMR SPECTRA
SYNTHESIS
BROMINATED ALIPHATIC HYDROCARBONS
ACTIVATION ENERGY
CHLORINATED ALIPHATIC HYDROCARBONS
DISULFIDES
IODINATED ALIPHATIC HYDROCARBONS
CARBON 13
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
COMPARATIVE EVALUATIONS
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DMSO
HYPERFINE STRUCTURE
IONIZATION
ISOMERIZATION
ISOMERS
J-J COUPLING
LITHIUM HYDROXIDES
MASS SPECTRA
METHYL IODIDE
POTASSIUM HYDROXIDES
SODIUM HYDROXIDES
SOLVENT PROPERTIES
STRUCTURAL CHEMICAL ANALYSIS
ALKALI METAL COMPOUNDS
CARBON ISOTOPES
CHEMICAL REACTIONS
COUPLING
ENERGY
EVEN-ODD NUCLEI
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXIDES
INTERMEDIATE COUPLING
ISOTOPES
KINETICS
LIGHT NUCLEI
LITHIUM COMPOUNDS
NUCLEI
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
POTASSIUM COMPOUNDS
REACTION KINETICS
SODIUM COMPOUNDS
SPECTRA
STABLE ISOTOPES
SULFOXIDES
YIELDS
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory