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Cluster complexes containing ynamine ligands. 2. Reactions of MeC triple bond CNMe sub 2 with M sub 3 (CO) sub 10 (. mu. sub 3 -S) (M = Fe, Ru, Os) and structural characterizations of Ru sub 2 (CO) sub 6 (. mu. -SC(NMe sub 2 )CMe), Ru sub 2 (CO) sub 6 (. mu. -SCMeC(NMe sub 2 )), and Os sub 3 (CO) sub 9 (. mu. sub 3 -MeC sub 2 NMe sub 2 )(. mu. sub 3 -S)

Journal Article · · Organometallics; (USA)
DOI:https://doi.org/10.1021/om00117a011· OSTI ID:6380370
; ; ;  [1]
  1. Univ. of South Carolina, Columbia (USA)
+ Show Author Affiliations

The reactions of the compounds M{sub 3}(CO){sub 10}({mu}{sub 3}-S) (1a, M = Fe; 1b, M = Ru) with MeC{sub 2}NMe{sub 2} yielded the products M{sub 2}(CO){sub 6}({mu}-SC(NMe{sub 2})CMe) (2a, M = Fe, 3%; 2b, M = Ru, 36%) and M{sub 3}(CO){sub 9}({mu}{sub 3}-MeC{sub 2}NMe{sub 2})({mu}{sub 3}-S) (3a, M = Fe, 30%; 3b, M = Ru, 14%). The reaction of Os{sub 3}(CO){sub 10}({mu}{sub 3}-S) (1c) with MeC{sub 2}NMe{sub 2} yielded only the trinuclear product Os{sub 3}(CO){sub 9}({mu}{sub 3}-MeC{sub 2}NMe{sub 2})({mu}{sub 3}-S) (3c, 87%). Compounds 2b and 3c were characterized by single-crystal X-ray diffraction analyses. Crystal data: for 2b, space group P{bar 1}, a = 9.189 (1) {angstrom}, b = 11.705 (3) {angstrom}, c = 8.213 (1) {angstrom}, {alpha} = 106.18 (1){degree}, {beta} = 110.06 (1){degree}, {gamma} = 79.60 (2){degree}, V = 793.3 (3) {angstrom}{sup 3}, Z = 2. For 3c, space group P{bar 1}, a = 9.397 (4) {angstrom}, b = 13.406 (7) {angstrom}, c = 8.914 (3) {angstrom}, {alpha} = 92.84 (4){degree}, {beta} = 115.20 (3){degree}, {gamma} = 97.54 (4){degree}, V = 1000.3 (8) {angstrom}{sup 3}, Z = 2.

OSTI ID:
6380370
Journal Information:
Organometallics; (USA), Journal Name: Organometallics; (USA) Vol. 9:3; ISSN 0276-7333; ISSN ORGND
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CHEMICAL REACTIONS
COMPLEXES
CRYSTAL STRUCTURE
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
INFORMATION
LIGANDS
MEASURING INSTRUMENTS
MEASURING METHODS
NUMERICAL DATA
OSMIUM COMPLEXES
RUTHENIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES