Treatment of ionic solutions over the entire miscibility range. [Lithium chlorates and water; tetra-n-butylammonium picrate and n-butyl alcohol]

Conference · Fri May 01 04:00:00 EDT 1981

OSTI ID:6373545

Pitzer, K S

Conductance and thermodynamic properties are considered for several ionic systems continuously miscible from the fused salt to dilute solution in water or another polar solvent. Over most of the composition range, the activities of the respective components of the ionic systems show the same patterns of behavior and can be represented by the same equations that were developed for nonelectrolytes. Consideration is also given to ionic systems of large but finite solubility, including mixed electrolytes. The dominant factor in the behavior of these systems is the strength of ion solvation in competition with intermolecular forces in the solvent and direct interionic forces. Strong ion solvation yields negative deviations from ideal solution behavior and vice versa.

• Research Organization: Lawrence Berkeley Lab., CA (USA)
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 6373545
• Report Number(s): LBL-12761; CONF-810589-1; ON: DE81023029
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALCOHOLS
ALKALI METAL COMPOUNDS
AMINES
AMMONIUM COMPOUNDS
BUTANOLS
CHARGED PARTICLES
CHLORATES
CHLORINE COMPOUNDS
ELECTRIC CONDUCTIVITY
ELECTRICAL PROPERTIES
HALOGEN COMPOUNDS
HIGH TEMPERATURE
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INTERMOLECULAR FORCES
IONS
LITHIUM COMPOUNDS
MEDIUM TEMPERATURE
NITRO COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
QUATERNARY COMPOUNDS
SOLVATION
SOLVENTS
THERMODYNAMIC PROPERTIES
VISCOSITY
WATER