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Adiabatic hyperspherical treatment of the H/sub 2/ /sup +/ molecule

Journal Article · · Phys. Rev. A; (United States)
The simplest molecule is treated theoretically using hyperspherical coordinates. It is argued, and demonstrated semiquantitatively, that the adiabatic body-frame approximation in hyperspherical coordinates is nearly identical to the Born-Oppenheimer approximation.
Research Organization:
Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803
OSTI ID:
6369388
Journal Information:
Phys. Rev. A; (United States), Journal Name: Phys. Rev. A; (United States) Vol. 26:5; ISSN PLRAA
Country of Publication:
United States
Language:
English

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Related Subjects

640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ADIABATIC APPROXIMATION
BORN-OPPENHEIMER APPROXIMATION
CATIONS
CHARGED PARTICLES
DIFFERENTIAL EQUATIONS
ELECTRONIC STRUCTURE
EQUATIONS
HYDROGEN IONS
HYDROGEN IONS 2 PLUS
IONS
MOLECULAR IONS
PARTIAL DIFFERENTIAL EQUATIONS
SCHROEDINGER EQUATION
WAVE EQUATIONS