Liquid phase oxidation of thiophenol and olefins by oxygen and t-butyl hydroperoxide

Conference · Tue Mar 31 23:00:00 EST 1987 · Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.; (United States)

OSTI ID:6367488

Mushrush, G W; Watkins, J M; Hazlett, R N; Hardy, D R; Eaton, H G

The stability of jet fuels is frequently dependent upon the nature of potential autoxidation pathways which can take place under aircraft operating conditions. This paper is concerned with the reaction between a primary autooxidation product, a hydroperoxide, with thiophenol in the presence of the active olefins indene and styrene. The reactions were carried out in deaerated benzene with t-butyl hydroperoxide or in benzene with an oxygen overpressure.

• Research Organization: The Naval Research Lab., Code 6180, Washington, DC 20375-5000
• OSTI ID: 6367488
• Report Number(s): CONF-870410-
• Journal Information: Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.; (United States), Journal Name: Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.; (United States) Vol. 32:1; ISSN ACFPA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AIRCRAFT
ALKENES
ALKYL RADICALS
ALKYLATED AROMATICS
AROMATICS
BENZENE
BUTYL RADICALS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CONDENSED AROMATICS
ELEMENTS
FUELS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN PEROXIDE
INDENE
JET ENGINE FUELS
KINETICS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDATION
OXYGEN
OXYGEN COMPOUNDS
PEROXIDES
PRESSURE DEPENDENCE
RADICALS
REACTION KINETICS
STABILITY
STYRENE
THIOPHENOLS