Outer-sphere interaction of aluminum and gallium solvates with competitive anions in 1,2-propanediol solutions

Journal Article · Tue Apr 01 00:00:00 EST 1986 · Sov. J. Coordinat. Chem.; (United States)

OSTI ID:6366788

Petrosyants, S P; Buslaeva, E R

The interaction of aluminum and gallium solvates with ..pi..-acid ligand in 1,2-propanediol solutions has been investigated. The formation of associates of hexacoordinate aluminum solvates depends on the solvation of the anions in the bulk of the solution or on the faces of the solvento complexes. In the case of gallium the association of the solvates with the anions is determined by two factors: the existence of a configurational equilibrium for the solvento complexes and the preferential solvation of the competitive ..pi..-acid ligands.

• OSTI ID: 6366788
• Journal Information: Sov. J. Coordinat. Chem.; (United States), Vol. 11:6; Other Information: Translated from Koordinatsionnaya Khimiya; 11: No.6, 755-760(Jun 1985)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM CHLORIDES
CATALYTIC EFFECTS
CONFIGURATION INTERACTION
ALUMINIUM COMPLEXES
NMR SPECTRA
FLUORINE COMPOUNDS
SOLVATION
GALLIUM CHLORIDES
GALLIUM COMPLEXES
GLYCOLS
SOLVENT PROPERTIES
CATALYSTS
CHEMICAL SHIFT
COMPLEXOMETRY
EQUILIBRIUM
ETHANOL
FLUORINE 19
HYDROFLUORIC ACID
HYDROGEN
ION EXCHANGE
LIGANDS
METHANOL
NUCLEAR SCREENING
POTASSIUM FLUORIDES
PROPANOLS
ALCOHOLS
ALKALI METAL COMPOUNDS
ALUMINIUM COMPOUNDS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
ELEMENTS
FLUORIDES
FLUORINE ISOTOPES
GALLIUM COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INORGANIC ACIDS
ISOTOPES
LIGHT NUCLEI
NONMETALS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
POTASSIUM COMPOUNDS
SCREENING
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties