Structure and conformation of dihydro aromatic compounds. 3. Cis- and trans-disubstituted 1,4-dihydrobenzenes, 1,4-dihydronaphthalenes, and 9,10-dihydroanthracenes
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The conformational effects of cis and trans substituents on 1,4-dihydrobenzene, 1,4-dihydronaphthalene, and 9,10-dihydroanthracene were investigated with an empirical force field. It is found that steric repulsions between the substituents and the ortho ring hydrogens (peri interactions) lead to complex structural behavior. The possibility of chair-like structures and the interconversion between chair and boat forms is discussed. 24 references, 8 figures, 1 table.
- Research Organization:
- Indiana Univ.-Purdue Univ., Indianapolis
- OSTI ID:
- 6364198
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 106:11; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Structure and conformation of dihydroaromatic compounds. 1-alkyl-1,4-dihydrobenzenes, 1-alkyl-1,4-dihydronaphthalenes, and 9-alkyl-9,10-dihydroanthracenes
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Journal Article
·
Thu Dec 31 23:00:00 EST 1981
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6301541
Transition metal catalysis of hydrogen shuttling in coal liquefaction. [1,4-dihydrobenzene, 1,4-dihydronaphthalene, 9,10-phenanthrene]
Technical Report
·
Mon Mar 31 23:00:00 EST 1986
·
OSTI ID:5640782
Transition metal catalysis of hydrogen shuttling in coal liquefaction: Quarterly technical progress report, 3/1/86-5/31/86. [1,4-dihydrobenzene, 1,4-dihydronaphthalene, 9,10-dihydroanthracene]
Technical Report
·
Tue Jul 01 00:00:00 EDT 1986
·
OSTI ID:7055579
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
640305 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Theory-- (-1987)
74 ATOMIC AND MOLECULAR PHYSICS
ANTHRACENE
AROMATICS
BENZENE
BOND ANGLE
CHEMICAL BONDS
CHEMICAL REACTIONS
CONDENSED AROMATICS
CONFORMATIONAL CHANGES
DATA
EXPERIMENTAL DATA
HYDROCARBONS
HYDROGEN COMPOUNDS
INFORMATION
INTERMOLECULAR FORCES
ISOMERIZATION
ISOMERS
MOLECULAR STRUCTURE
NAPHTHALENE
NUMERICAL DATA
ORGANIC COMPOUNDS
STEREOCHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
640305 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Theory-- (-1987)
74 ATOMIC AND MOLECULAR PHYSICS
ANTHRACENE
AROMATICS
BENZENE
BOND ANGLE
CHEMICAL BONDS
CHEMICAL REACTIONS
CONDENSED AROMATICS
CONFORMATIONAL CHANGES
DATA
EXPERIMENTAL DATA
HYDROCARBONS
HYDROGEN COMPOUNDS
INFORMATION
INTERMOLECULAR FORCES
ISOMERIZATION
ISOMERS
MOLECULAR STRUCTURE
NAPHTHALENE
NUMERICAL DATA
ORGANIC COMPOUNDS
STEREOCHEMISTRY