Radiolysis of mixtures of carbon dioxide and hydrogen sulfide

Journal Article · Mon Feb 29 23:00:00 EST 1988 · High Energy Chem. (Engl. Transl.); (United States)

OSTI ID:6364085

Rustamov, V R; Kerimov, V K; Kurbanov, M A; Gezalov, Kh B; Nasirova, Kh Ya; Gadzhieva, N N

The radiolysis of CO/sub 2/-H/sub 2/S mixtures (5-50 vol. %) was investigated. It was shown that H/sub 2/S is an efficient scavenger of the oxygen formed during the radiolysis of CO/sub 2/. It was established that in the radiolysis of CO/sub 2/-H/sub 2/S mixtures (25-50 vol %) the nature of the products formed depends on the temperature during irradiation: At room temperature the main products are carbon oxysulfide (SCO) and hydrogen; increasing the temperature to 200/sup 0/C leads to the production of synthesis gas (H/sub 2/ + CO) and elemental sulfur. The total yield of radiolysis products amounts to 9.2-14.4 molecules per 100 eV.

• OSTI ID: 6364085
• Journal Information: High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 21:5; ISSN HIECA
• Country of Publication: United States
• Language: English

Related Subjects

03 NATURAL GAS
030300 -- Natural Gas-- Drilling
Production
& Processing
08 HYDROGEN
080100 -- Hydrogen-- Production
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
COBALT 60
COBALT ISOTOPES
DECOMPOSITION
DESULFURIZATION
DISPERSIONS
ELECTROMAGNETIC RADIATION
ELEMENTS
ENERGY SOURCES
FLUIDS
FOSSIL FUELS
FUEL GAS
FUELS
GAMMA RADIATION
GAS FUELS
GASES
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGEN PRODUCTION
HYDROGEN SULFIDES
INTERMEDIATE MASS NUCLEI
INTERNAL CONVERSION RADIOISOTOPES
IONIZING RADIATIONS
IRRADIATION
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
MINUTES LIVING RADIOISOTOPES
MIXTURES
NATURAL GAS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
OXIDES
OXYGEN
OXYGEN COMPOUNDS
OXYSULFIDES
PURIFICATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
RADIOISOTOPES
RADIOLYSIS
SULFIDES
SULFUR
SULFUR COMPOUNDS
SYNTHESIS GAS
TEMPERATURE DEPENDENCE
YEARS LIVING RADIOISOTOPES
YIELDS