Calculations of chemisorption and the elementary acts of catalytic reactions within the framework of a cluster model. XI. Dehydration of ethyl alcohol
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6360287
Within the framework of the CNDO/BW method and of a cluster model, this article discusses the energetics of the intermediate structures in the dehydration of ethyl alcohol over alumino-silicate catalysts. It is shown that during coordination there ia a selective weakening of the C - O and C..beta.. - H bonds, which promotes the dehydration of ethyl alchol to an unsaturated hydrocarbon. The calculation argues in support of the possibility of a synchronous mechanism of the reaction in question.
- Research Organization:
- N.D. Zelinskii Inst. of Organic Chemistry, Moscow
- OSTI ID:
- 6360287
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 21:5; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
090210 -- Alcohol Fuels-- Properties-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALCOHOLS
ALUMINIUM COMPOUNDS
ALUMINIUM SILICATES
CATALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISORPTION
DEHYDRATION
ETHANOL
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
MINERALS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
SILICATES
SILICON COMPOUNDS
SORPTION
ZEOLITES
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALCOHOLS
ALUMINIUM COMPOUNDS
ALUMINIUM SILICATES
CATALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISORPTION
DEHYDRATION
ETHANOL
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
MINERALS
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
SILICATES
SILICON COMPOUNDS
SORPTION
ZEOLITES