Synthesis of ammonium 5-oxo-1,3,2,5-dioxaborataphosphorinanes

Journal Article · Sun Apr 20 04:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:6357136

Arbuzov, B A; Nikonov, G N; Erastov, O A

The discovery of a basic catalysis for the reaction of hydroxyalkylphosphine oxides with boric acid esters opens up new possibilities for synthesizing boroxyalkyl derivatives of phosphorus. In particular, the introduction of amines into the reaction is interesting, since in this case, in the presence of a free hydroxyalkyl grouping in the product, complex-salt tautomerism is possible, causing varied reactivity of the compounds. In the present work it was shown that the reaction of bis(..cap alpha..-hydroxyalkyl)phenylphosphine oxides with i-BuOBPh/sub 2/ in the presence of amines led to the formation of ammonium 5-oxo-1,3,2,5-dioxaborataphosphorinanes. The structure was established from the data of elemental analysis and IR and P-31 NMR spectra.

• Research Organization: A.B. Arbuzov Institute of Organic and Physical Chemistry, Kazan, USSR
• OSTI ID: 6357136
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:10; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPLEXES
AMINES
AMMONIUM COMPLEXES
AZINES
BINDING ENERGY
BORIC ACID
CARBOXYLIC ACID ESTERS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
COMPLEXES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
ESTERS
FERMIONS
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
ISOTOPES
KINETICS
LEPTONS
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PYRIDINE
PYRIDINES
REACTION KINETICS
SODIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
VALENCE
YIELDS