Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions--3. Electronic and catalytic properties of nickel catalysts. [Butylene oxides]
A relationship between a parameter ..delta.. q and the ESCA chemical shift was derived from available extended Hueckel calculation results and ESCA data for nickel boride and nickel phosphide. The ..delta.. q parameter described the change in electron density at the nickel metal that occurred due to the electron transfer between nickel and the other element. The ..delta.. q parameters were estimated for Rayney nickel and Urushibara nickel, which contained aluminum and zinc alloy components, respectively, from product ratios and rate ratios measured for cyclohexene and cyclooctene hydrogenation on these catalysts. The ..delta.. q parameter correlated the increase in specific activities with increasing electron density in the hydrogenation of styrene, the increase in poisoning coefficient for carbon disulfide and triphenylphosphine with increasing electron density in the hydrogenation of styrene, and the selectivity for n-butyl alcohol in the hydrogenation of 1,2-butylene oxide on various nickel catalysts.
- Research Organization:
- Osaka Univ.
- OSTI ID:
- 6356801
- Journal Information:
- J. Catal.; (United States), Vol. 64:2
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CYCLOALKENES
HYDROGENATION
EPOXIDES
CATALYSTS
NICKEL ALLOYS
CATALYTIC EFFECTS
NICKEL BORIDES
NICKEL PHOSPHIDES
STYRENE
ALUMINIUM ALLOYS
BUTANOLS
CALCULATION METHODS
CARBON SULFIDES
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
CORRELATIONS
ELECTRON DENSITY
ELECTRON TRANSFER
NICKEL
PHOSPHINES
QUANTITY RATIO
SPECIFICITY
SURFACE PROPERTIES
ZINC ALLOYS
ALCOHOLS
ALKENES
ALKYLATED AROMATICS
ALLOYS
AROMATICS
BORIDES
BORON COMPOUNDS
CARBON COMPOUNDS
CHALCOGENIDES
CHEMICAL REACTIONS
ELEMENTS
HYDROCARBONS
HYDROXY COMPOUNDS
METALS
NICKEL COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PNICTIDES
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
YIELDS
400201* - Chemical & Physicochemical Properties
400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)