Rotationally resolved isotope effect in the hot atom collisional excitation of CO/sub 2/ (00/sup 0/1) by time-dependent diode laser spectroscopy

Journal Article · Sat Aug 01 00:00:00 EDT 1987 · J. Chem. Phys.; (United States)

OSTI ID:6348711

Hewitt, S A; Hershberger, J F; Flynn, G W; Weston, Jr, R E

High resolution diode laser spectoscopy is used to probe the rotational structure of the CO/sub 2/(00/sup 0/1) state, produced in the inelastic scattering of hot deuterium atoms and CO/sub 2/(00/sup 0/0). A preference for excitation of high J levels relative to low J levels of CO/sub 2/(00/sup 0/1) by hot deuterium atoms compared to hot hydrogen atoms was observed. (AIP)

• Research Organization: Department of Chemistry and Columbia Radiation Laboratory, Columbia University, New York, New York 10027
• OSTI ID: 6348711
• Journal Information: J. Chem. Phys.; (United States), Vol. 87:3
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
ATOM-MOLECULE COLLISIONS
ENERGY TRANSFER
CARBON DIOXIDE
DEUTERIUM
ISOTOPE EFFECTS
HYDROGEN SULFIDES
PHOTOLYSIS
LASER SPECTROSCOPY
ROTATIONAL STATES
ATOM COLLISIONS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
COLLISIONS
DECOMPOSITION
ENERGY LEVELS
EXCITED STATES
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
MOLECULE COLLISIONS
NUCLEI
ODD-ODD NUCLEI
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
SPECTROSCOPY
STABLE ISOTOPES
SULFIDES
SULFUR COMPOUNDS
640304* - Atomic
Molecular & Chemical Physics- Collision Phenomena