Structural consequences of oxidation in photosynthetic models. Crystal structure of (perchlorato)-(5,10,15,20-tetraphenylporphinato)magnesium(II)
Journal Article
·
· Inorg. Chem.; (United States)
- Brookhaven National Lab., Upton, NY
This report is an X-ray determination of a magnesium porphyrin radical, (perchlorato)(5,10,15,20-tetraphenylporphinato)magnesium(II), MgTPP/sup +/.ClO/sub 4//sup -5/ as a model of the structural and stereochemical consequences of the loss of an electron in photosynthetic chromophores.
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 6347900
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 22:2; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALINE EARTH METAL COMPLEXES
BOND LENGTHS
CHEMICAL REACTIONS
COMPLEXES
CRYSTAL STRUCTURE
CRYSTALLOGRAPHY
DIMENSIONS
LENGTH
MAGNESIUM COMPLEXES
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
PARAMETRIC ANALYSIS
400201* -- Chemical & Physicochemical Properties
ALKALINE EARTH METAL COMPLEXES
BOND LENGTHS
CHEMICAL REACTIONS
COMPLEXES
CRYSTAL STRUCTURE
CRYSTALLOGRAPHY
DIMENSIONS
LENGTH
MAGNESIUM COMPLEXES
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDATION
PARAMETRIC ANALYSIS