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Superconductivity in amorphous+crystalline Ti-(Nb or V)-Si-B ductile alloys obtained by rapid quenching from the melt

Journal Article · · J. Appl. Phys.; (United States)
DOI:https://doi.org/10.1063/1.329303· OSTI ID:6346576

Ductile superconductors with a duplex structure consisting of amorphous and bcc phases have been found in rapidly quenched alloys of the Ti/sub 70-x/Nb/sub 30/(Si-B)/sub x/ and Ti/sub 60hyphenx/V/sub 40/(Si-B)/sub x/ quaternary systems. Continuous ribbons of these alloys were produced in the form of about 1-mm width and 0.02-mm thickness using a modified single roller quenching apparatus. The silicon content in these duplex alloys was limited to the range between about 7 and 19 at. % and the boron content was in the range of about 0 to 9 at. %. The superconducting transition temperature T/sub c/ increased with decreasing metalloid content and/or with replacement of silicon by boron. The highest values obtained were 7.3 K for Ti/sub 57/Nb/sub 30/Si/sub 10/B/sub 3/ and 4.7 K for Ti/sub 45/V/sub 40/Si/sub 8/B/sub 7/, which are much higher than those of Ti-Nb and Ti-V base amorphous superconductors. The upper critical magnetic field H/sub c/2 and the critical current density J/sub c/ for the Ti/sub 55/Nb/sub 30/Si/sub 7/B/sub 8/ alloy were about 5.1 x 10/sup 6/ A/m at 4.2 K and of the order 3.5 x 10/sup 4/ A/cm/sup 2/ at zero applied field and 4.2 K. Although the superconducting properties of the duplex alloys are still insufficient for practical use, the information that the duplex structure produces a remarkable improvement in the superconducting properties without a detectable change or loss of ductility seems to be very important from the technological point of view.

Research Organization:
The Research Institute for Iron, Steel and Other Metals, Tohoku University, Sendai 980, Japan
OSTI ID:
6346576
Journal Information:
J. Appl. Phys.; (United States), Journal Name: J. Appl. Phys.; (United States) Vol. 52:7; ISSN JAPIA
Country of Publication:
United States
Language:
English